Aryloxide-Facilitated Catalyst Turnover in Enantioselective α,β-Unsaturated Acyl Ammonium CatalysisA. Matviitsuk, M. D. Greenhalgh, D.-J. Barrios Antúnez, A. M. Z. Slawin and A. D. SmithAngew. Chem. Int. Ed., 2017, DOI: 10.1002/ange.201706402N- to C-Sulfonyl Photoisomerisation of Dihydropyridinones: A Synthetic and Mechanistic StudyP.-P. Yeh, J. E. Taylor, D. G. Stark, D. S. B. Daniels, C. Fallan, J. C. Walton and A. D. SmithOrg. Biomol. Chem., 2017Tandem Pd and Isothiourea Relay Catalysis: Enantioselective Synthesis of α-Amino Acid Derivatives via Allylic Amination and [2,3]-Sigmatropic RearrangementS. S. M. Spoehrle, T. H. West, J. E. Taylor, A. M. Z. Slawin, A. D. SmithJ. Am. Chem. Soc., 2017, DOI: 10.1021/jacs.7b05619Aryloxide Promoted Catalyst Turnover in Lewis Base OrganocatalysisW. C. Hartley, T. J. C. O’Riordan and A. D. SmithSynthesis, 2017, 49, 3303-3310Catalytic Enantioselective [2,3]-Rearrangements of Allylic Ammonium Ylides: A Mechanistic and Computational StudyT. H. West, D. M. Walden, J. E. Taylor, A. C. Brueckner, R. C. Johnson, P. H.-Y. Cheong, G. C. Lloyd-Jones and A. D. SmithJ. Am. Chem. Soc., 2017, DOI: 10.1021/jacs.6b11851Isothiourea-catalysed chemo- and enantioselective [2,3]-sigmatropic rearrangements of N,N-diallyl allylic ammonium ylidesT. H. West, S. S. M. Spoehrle and A. D. SmithTetrahedron, 2017, DOI: 10.1016/j.tet.2017.01.062Enantioselective NHC-Catalysed Redox [4+2]-Hetero-Diels-Alder Reactions using α-Aroyloxyaldehydes and Unsaturated KetoestersJ. E. Taylor, A. T. Davies, J. J. Douglas, G. Churchill and A. D. SmithTetrahedron: Asymmetry, 2017, 28, 355-3666-exo-trig Michael Addition-Lactonizations for Catalytic Enantioselective Chromenone SynthesisR. M.Neyyappadath, D. B.Cordes, A. M. Z. Slawin and A. D. SmithChem. Commun., 2017, DOI: 10.1039/c6cc10178jEnantioselective N-heterocyclic carbene catalyzed formal [3+2] cycloaddition using α-aroyloxyaldehydes and oxaziridinesR. W. F. Kerr, M. D. Greenhalgh, A. M. Z. Slawin, P. L. Arnold and A. D. SmithTetrahedron: Asymmetry, 2017, 28, 125-134Isothiourea-Catalysed Acylative Kinetic Resolution of Aryl-Alkenyl (sp2 vs sp2) Substituted Secondary AlcoholsS. F. Musolino, O. S. Ojo, N. J. Westwood, J. E. Taylor and A. D. SmithChem. Eur. J., 2016, 22, 18916-18922Enantioselective Isothiourea Catalysed Michael-Michael-Lactonisation Cascade; Synthesis of δ-Lactones and 1,2,3,4-Substituted CyclopentanesE. R. T. Robinson, A. B. Frost, P. Elías-Rodríguez and A. D. SmithSynthesis, 2017, 49, 409-423Exploiting the Imidazolium Effect in Base-free Ammonium Enolate Generation: Synthetic and Mechanistic StudiesC. M. Young, D. G. Stark, T. H. West, J. E. Taylor and A. D. SmithAngew. Chem. Int. Ed., 2016, 55, 14394-14399Enantioselective Stereodivergent Nucleophile-Dependent Isothiourea-Catalysed Domino ReactionsA. Matviitsuk, J. E. Taylor, D. B. Cordes, A. M. Z. Slawin and A. D. SmithChem. Eur. J., 2016, 22, 17748-17757Enantioselective Isothiourea-Catalysed trans-Dihydropyridinone Synthesis using Saccharin-derived Ketimines: Scope and LimitationsD. G. Stark, C. M. Young, T. J. C. O\'Riordan, A. M. Z. Slawin and A. D. SmithOrg. Biomol. Chem., 2016, 14, 8068-8073Catalytic Enantioselective Synthesis of Pyrrolizine Carboxylates using Isothiourea Catalysis: A Synthetic and Computational StudyD. G. Stark, P. Williamson, E. R. Gayner, S. F. Musolino, R. W. F. Kerr, J. E. Taylor, A. M. Z. Slawin, T. J. C. O\'Riordan, S. A. MacGregor and A. D. SmithOrg. Biomol. Chem., 2016, 14, 8957-8965Non-Bonding 1,5-S•••O Interactions Govern Chemo- and Enantioselectivity in Isothiourea-Catalyzed Annulations of BenzazolesE. R. T. Robinson, D. M. Walden, C. Fallan, M. D. Greenhalgh, P. H.-Y. Cheong and A. D. SmithChem. Sci., 2016, 7, 6919-6927Enantioselective Synthesis of 2,3-Disubstituted trans-2,3-Dihydrobenzofurans Using a Brønsted Base/Thiourea Bifunctional CatalystD. -J. Barrios Antúnez, M. D. Greenhalgh, C. Fallan, A. M. Z. Slawin and A. D. SmithOrg. Biomol. Chem., 2016, 14, 7268-7274Quinidine-Catalysed Enantioselective Synthesis of 6- and 4-Trifluoromethyl-Substituted DihydropyransK. Kasten, D. B. Cordes, A. M. Z. Slawin and A. D. SmithEur. J. Org. Chem., 2016, 21, 3619-3624Isothiourea-Mediated Organocatalytic Michael Addition–Lactonization on a Surface: Modification of SAMs on Silicon Oxide SubstratesR. Chisholm, J. D. Parkin, A. D. Smith and G. HähnerLangmuir, 2016, 32, 3130-3138A Substrate Mimic Allows High-Throughput Assay of the FabA Protein and Consequently the Identification of a Novel Inhibitor of Pseudomonas aeruginosa FabAL. Moynie, A. G. Hope, K. Finzel, J. Schmidberger, S. M. Leckie, G. Schneider, M. D. Burkhart, A. D. Smith, D. W. Gray and J. H. NaismithJ. Mol. Biol., 2016, 428, 108-120
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